Crystal mis-orientation provides a toughening mechanism. a Schematic of the mechanisms: co-oriented crystals (blue) enable crack propagation across different crystals, precisely because they are co-oriented. When crystals are mis-oriented (colors), instead, cracks deflect at crystal interfaces, thus they cannot propagate or grow over long distances, and the material is tougher. b Molecular dynamics simulations of grain boundaries, where hydroxyapatite crystals are mis-oriented by 0, 14, or 47. Notice that the crack starting from the bottom propagates straight through the 0 interface, is deflected at the 14, and again not deflected at the 47 interface. See Supplementary Movies 1, 2, 3
Kaleidagraph 4 0 Crack 6
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